Yes, probability is a KEY tool when playing any card game (from BLackJack, Poker, etc to Elements).
The thing is "its just probability". It help on the theoretical side; but after having a solid build, decision are made on the experience of the deck.
I'll use an example to explain myself:
Suppose you are playing Blackjack 1v1 (vs croupier).
According to probability the best strategy is to call for a card if you sum up 16 or less, and stay if you get 17 to 21.
Nevertheless, sometimes you may want to draw a card although you have 17 (running a high risk of going over 21)
And that is based on experiencie.
Yet as humans we are faulty, and there are many ways to exploits your human flaws. For example: using gambler falacy; trick you with the way you may win money (only costs you $1 to play and you can win $50, though odds of winning are 0,12).
Also I want to explain that when we express probability; for example 30%. That means the chances of something happening is THAT (a relative number). It doesn't mean that if you repeat it 100 times, 30 of them will succed. (That has its own probability, which is by the way: chances of having 30 succes in 100 trys, with a p=0,3: 0.086783864 or 8,7%)